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Captain was a military, naval or police rank.
Named Captains
- Henry Avery (TV: The Smugglers)
- Bates (TV: The Curse of Fenric)
- Brent (PROSE: Time and Relative)
- Britt (AUDIO: The Runaway Train)
- Chin Lee (TV: The Mind of Evil)
- Cook (TV: The Greatest Show in the Galaxy)
- Dent (TV: Colony in Space)
- Edal (TV: The Savages)
- Harker (TV: The Claws of Axos)
- Jack Harkness (TV: The Empty Child)
- John Hart (Kiss Kiss, Bang Bang) (TV: Kiss Kiss, Bang Bang)
- John Hart (The Sea Devils) (TV: The Sea Devils)
- Harvey (PROSE: Invaders Invisible)
- Hawkins (TV: Doctor Who and the Silurians)
- Hopper (TV: The Tomb of the Cybermen)
- Kent Howard (PROSE: Endgame)
- Jabel (TV: The Face of Evil)
- Knight (TV: The Web of Fear)
- Erisa Magambo (TV: Turn Left)
- Maitland (TV: The Sensorites)
- Jimmy Munro (TV: Spearhead from Space)
- Samuel Pike (TV: The Smugglers)
- Marion Price (TV: The Sontaran Stratagem / The Poison Sky)
- Ransom (TV: The War Games)
- Revere (TV: Frontios)
- Rigg (TV: Nightmare of Eden)
- Rossini (TV: The Masque of Mandragora)
- Sorin (TV: The Curse of Fenric)
- Stapley (TV: Time-Flight)
- Striker (TV: Enlightenment)
- Jimmy Turner (TV: The Invasion)
- Urquhart (TV: Time-Flight)
- Vay (PROSE: The Dalek Factor)
- Walker (WC: Tardisode 8)
- Wrack (TV: Enlightenment)
- Mike Yates (TV: Terror of the Autons)
Unnamed captains
- The Captain (TV: The Pirate Planet)
- Alien Space Captain (TV: The Ambassadors of Death)
- Atlantean captain (PROSE: The Lost Ones)
- Aztec captain (TV: The Aztecs)
- Captain (TV: Carnival of Monsters)
- Captain (AUDIO: Deimos / The Resurrection of Mars)
- Captain of the Guard (TV: The Massacre of St Bartholomew's Eve)
- Captain (TV: The War Machines)
- Captain (AUDIO: The Wreck of the Titan)
- Draconian captain (TV: Frontier in Space)
- Earth cruiser captain (TV: Frontier in Space)
- Guard Captain (TV: The Curse of Peladon)
- Guard Captain (TV: The Enemy of the World)
- Guard Captain (TV: The Monster of Peladon)
- Guard Captain (TV: Planet of the Spiders)
- Judoon captain (several individuals)
- Shrieve captain (TV: The Ribos Operation)
- Space Captain (TV: The Rescue)
Fictional captains
- Captain Jack Harkaway (TV: The Mind Robber)
- Captain Millennium (PROSE: Tragedy Day)
- Captain Scarlet (AUDIO: The Dead Line, TV: Children of Earth)
