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Diamonds were a form of crystallised carbon and one of the most valuable substances in the universe.
Only one of every 10.000 diamonds that were minded on Earth were coloured. Most of these got their colour from chemical impurities or defects in the stone itselfs. However black diamonds were different. Their colour came from the presence of tiny minerals inclusions. (AUDIO: The Time Capsule)
Around the turn of the 20th century, the Fourth Doctor used a diamond as a focusing piece to turn Fang Rock lighthouse into a carbon oscillator. He obtained the diamonds from Henry Palmerdale, who carried them as a secure currency, and used the laser to destroy a Rutan mothership. (TV: Horror of Fang Rock)
To escape the Last Great Time War, the Time Lords sent a White-Point Star in the form of a diamond through the time lock to the Master. He used it to amplify the signal and bring them to Earth, but the Tenth Doctor shot it with Wilfred Mott's old service revolver, destroying it and the link. (TV: The End of Time)
The planet Sartor was rich in diamonds, which were mined by the human colonists. Quarsian pirates attempted to steal the diamonds, but were defeated by the Tenth Doctor. (COMIC: The Diamonds of Sartor / Quarsian Mission / Android of Death)